Radon - 86Rn: properties of free atoms
Radon atoms have 86 electrons and the shell structure is 2.8.18.32.18.8.
The ground state electron configuration of ground state gaseous neutral radon is [Xe].4f14.5d10.6s2.6p6 and the term symbol is 1S0.
Atomic spectrum
A representation of the atomic spectrum of radon.
Ionisation Energies and electron affinity
The electron affinity of radon is 0 kJ mol‑1. The ionisation energies of radon are given below.
Effective Nuclear Charges
The following are "Clementi-Raimondi" effective nuclear charges, Zeff. Follow the hyperlinks for more details and for graphs in various formats.
1s | 84.33 | ||||||
---|---|---|---|---|---|---|---|
2s | 63.41 | 2p | 81.44 | ||||
3s | 61.09 | 3p | 62.28 | 3d | 72.60 | ||
4s | 50.15 | 4p | 49.30 | 4d | 47.94 | 4f | 48.33 |
5s | 33.89 | 5p | 31.97 | 5d | 27.35 | ||
6s | 18.32 | 6p | 16.08 | ||||
7s |
References
These effective nuclear charges, Zeff, are adapted from the following references:
- E. Clementi and D.L.Raimondi, J. Chem. Phys. 1963, 38, 2686.
- E. Clementi, D.L.Raimondi, and W.P. Reinhardt, J. Chem. Phys. 1967, 47, 1300.
Electron binding energies
Label | Orbital | eV [literature reference] |
---|---|---|
K | 1s | 98404 [1] |
L I | 2s | 18049 [1] |
L II | 2p1/2 | 17337 [1] |
L III | 2p3/2 | 14619 [1] |
M I | 3s | 4482 [1] |
M II | 3p1/2 | 4159 [1] |
M III | 3p3/2 | 3538 [1] |
M IV | 3d3/2 | 3022 [1] |
M V | 3d5/2 | 2892 [1] |
N I | 4s | 1097 [2] |
N II | 4p1/2 | 929 [2] |
N III | 4p3/2 | 768 [2] |
N IV | 4d3/2 | 567 [2] |
N V | 4d5/2 | 541 [2] |
N VI | 4f5/2 | 238 [2] |
N VII | 4f7/2 | 238 [2] |
O I | 5s | 214 [2] |
O II | 5p1/2 | 164 [2] |
O III | 5p3/2 | 127 [2] |
O IV | 5d3/2 | 48 [2] |
O V | 5d5/2 | 48 [2] |
P I | 6s | 26 [1] |
Notes
I am grateful to Gwyn Williams (Jefferson Laboratory, Virginia, USA) who provided the electron binding energy data. The data are adapted from references 1-3. They are tabulated elsewhere on the WWW (reference 4) and in paper form (reference 5).
References
- J. A. Bearden and A. F. Burr, "Reevaluation of X-Ray Atomic Energy Levels," Rev. Mod. Phys., 1967, 39, 125.
- M. Cardona and L. Ley, Eds., Photoemission in Solids I: General Principles (Springer-Verlag, Berlin) with additional corrections, 1978.
- Gwyn Williams WWW table of values
- D.R. Lide, (Ed.) in Chemical Rubber Company handbook of chemistry and physics, CRC Press, Boca Raton, Florida, USA, 81st edition, 2000.
- J. C. Fuggle and N. Mårtensson, "Core-Level Binding Energies in Metals," J. Electron Spectrosc. Relat. Phenom., 1980, 21, 275.