Vanadium tetrachloride

The following are some synonyms of vanadium tetrachloride:

The oxidation number of vanadium in vanadium tetrachloride is 4.

Synthesis

2V₂O₅ + 5C + 8Cl₂ (880°C) → 4VCl₄ + 5CO₂(g)

Solid state structure

• Geometry of vanadium: 4 coordinate: tetrahedral
• Prototypical structure:

Element analysis

The table shows element percentages for VCl₄ (vanadium tetrachloride).

Isotope pattern for VCl₄

The chart below shows the calculated isotope pattern for the formula VCl₄ with the most intense ion set to 100%.

References

The data on these compounds pages are assembled and adapted from the primary literature and several other sources including the following.

• R.T. Sanderson in Chemical Periodicity, Reinhold, New York, USA, 1960.
• N.N. Greenwood and A. Earnshaw in Chemistry of the Elements, 2nd edition, Butterworth, UK, 1997.
• F.A. Cotton, G. Wilkinson, C.A. Murillo, and M. Bochmann, in Advanced Inorganic Chemistry, John Wiley & Sons, 1999.
• A.F. Trotman-Dickenson, (ed.) in Comprehensive Inorganic Chemistry, Pergamon, Oxford, UK, 1973.
• R.W.G. Wyckoff, in Crystal Structures, volume 1, Interscience, John Wiley & Sons, 1963.
• A.R.West in Basic solid state chemistry Chemistry, John Wiley & Sons, 1999.
• A.F. Wells in Structural inorganic chemistry, 4th edition, Oxford, UK, 1975.
• J.D.H. Donnay, (ed.) in Crystal data determinative tables, ACA monograph number 5, American Crystallographic Association, USA, 1963.
• D.R. Lide, (ed.) in Chemical Rubber Company handbook of chemistry and physics, CRC Press, Boca Raton, Florida, USA, 77th edition, 1996.
• J.W. Mellor in A comprehensive treatise on inorganic and theoretical chemistry, volumes 1-16, Longmans, London, UK, 1922-1937.
• J.E. Macintyre (ed.) in Dictionary of inorganic compounds, volumes 1-3, Chapman & Hall, London, UK, 1992.