Trilithium nitride
- Formula: Li3N
- Hill system formula: Li3N1
- CAS registry number: [26134-62-3]
- Formula weight: 34.83
- Class: nitride
- Colour: purple or red
- Appearance: crystalline solid
- Melting point: 813°C
- Boiling point:
- Density: 1270 kg m-3
The following are some synonyms of trilithium nitride:
- trilithium nitride
- lithium(I) nitride
- lithium nitride
The oxidation number of lithium in trilithium nitride is 1.
Synthesis
One way to make lithium nitride is by the rection of lithium metal with pressurized nitrogen gas (> 10 atmospheres) at high temperatures
6Li(l) + N2(g) (800°C, 10 atm) → 2Li3N(s)
Solid state structure
- Geometry of lithium:
- Prototypical structure:
Element analysis
The table shows element percentages for Li3N (trilithium nitride).
| Element | % |
|---|---|
| Li | 59.79 |
| N | 40.21 |
Isotope pattern for Li3N
The chart below shows the calculated isotope pattern for the formula Li3N with the most intense ion set to 100%.
References
The data on these compounds pages are assembled and adapted from the primary literature and several other sources including the following.
- R.T. Sanderson in Chemical Periodicity, Reinhold, New York, USA, 1960.
- N.N. Greenwood and A. Earnshaw in Chemistry of the Elements, 2nd edition, Butterworth, UK, 1997.
- F.A. Cotton, G. Wilkinson, C.A. Murillo, and M. Bochmann, in Advanced Inorganic Chemistry, John Wiley & Sons, 1999.
- A.F. Trotman-Dickenson, (ed.) in Comprehensive Inorganic Chemistry, Pergamon, Oxford, UK, 1973.
- R.W.G. Wyckoff, in Crystal Structures, volume 1, Interscience, John Wiley & Sons, 1963.
- A.R.West in Basic solid state chemistry Chemistry, John Wiley & Sons, 1999.
- A.F. Wells in Structural inorganic chemistry, 4th edition, Oxford, UK, 1975.
- J.D.H. Donnay, (ed.) in Crystal data determinative tables, ACA monograph number 5, American Crystallographic Association, USA, 1963.
- D.R. Lide, (ed.) in Chemical Rubber Company handbook of chemistry and physics, CRC Press, Boca Raton, Florida, USA, 77th edition, 1996.
- J.W. Mellor in A comprehensive treatise on inorganic and theoretical chemistry, volumes 1-16, Longmans, London, UK, 1922-1937.
- J.E. Macintyre (ed.) in Dictionary of inorganic compounds, volumes 1-3, Chapman & Hall, London, UK, 1992.