Chlorocarbonylbis(triphenylphosphine) iridium
- Formula: IrCl(CO)(PPh3)2
- Hill system formula: C37Cl1H30Ir1O1P2
- CAS registry number: [14871-41-1]
- Formula weight: 780.251
- Class: complex organometallic
- Colour:
- Appearance: crystalline solid
- Melting point: 215°C
- Boiling point:
- Density:
The following are some synonyms of chlorocarbonylbis(triphenylphosphine) iridium:
- chlorocarbonylbis(triphenylphosphine) iridium
- chlorocarbonylbis(triphenylphosphine) iridium(I)
- Vaska's catalyst
- Vaska's complex
The oxidation number of iridium in chlorocarbonylbis(triphenylphosphine) iridium is 1.
Synthesis
Not available
Element analysis
The table shows element percentages for IrCl(CO)(PPh3)2 (chlorocarbonylbis(triphenylphosphine) iridium).
| Element | % |
|---|---|
| C | 56.96 |
| Cl | 4.54 |
| H | 3.88 |
| Ir | 24.64 |
| O | 2.05 |
| P | 7.94 |
Isotope pattern for IrCl(CO)(PPh3)2
The chart below shows the calculated isotope pattern for the formula IrCl(CO)(PPh3)2 with the most intense ion set to 100%.
References
The data on these compounds pages are assembled and adapted from the primary literature and several other sources including the following.
- R.T. Sanderson in Chemical Periodicity, Reinhold, New York, USA, 1960.
- N.N. Greenwood and A. Earnshaw in Chemistry of the Elements, 2nd edition, Butterworth, UK, 1997.
- F.A. Cotton, G. Wilkinson, C.A. Murillo, and M. Bochmann, in Advanced Inorganic Chemistry, John Wiley & Sons, 1999.
- A.F. Trotman-Dickenson, (ed.) in Comprehensive Inorganic Chemistry, Pergamon, Oxford, UK, 1973.
- R.W.G. Wyckoff, in Crystal Structures, volume 1, Interscience, John Wiley & Sons, 1963.
- A.R.West in Basic solid state chemistry Chemistry, John Wiley & Sons, 1999.
- A.F. Wells in Structural inorganic chemistry, 4th edition, Oxford, UK, 1975.
- J.D.H. Donnay, (ed.) in Crystal data determinative tables, ACA monograph number 5, American Crystallographic Association, USA, 1963.
- D.R. Lide, (ed.) in Chemical Rubber Company handbook of chemistry and physics, CRC Press, Boca Raton, Florida, USA, 77th edition, 1996.
- J.W. Mellor in A comprehensive treatise on inorganic and theoretical chemistry, volumes 1-16, Longmans, London, UK, 1922-1937.
- J.E. Macintyre (ed.) in Dictionary of inorganic compounds, volumes 1-3, Chapman & Hall, London, UK, 1992.