Digold hexabromide
- Formula: [AuBr3]2
- Hill system formula: Au2Br6
- CAS registry number: [10294-28-7]
- Formula weight: 873.357
- Class: bromide
- Colour: red-brown
- Appearance: crystalline solid
- Melting point: 160°C (decomposes)
- Boiling point:
- Density:
The following are some synonyms of digold hexabromide:
- digold hexabromide
- gold(III) bromide
- auric bromide
- gold bromide
- gold tribromide
The oxidation number of gold in digold hexabromide is 3.
Synthesis
Au + Br2 (140°C) → Au2Br6
dimer [11092-53-8]
Solid state structure
- Geometry of gold: 4 coordinate: square planar
- Prototypical structure:
Element analysis
The table shows element percentages for [AuBr3]2 (digold hexabromide).
Element | % |
---|---|
Au | 45.11 |
Br | 54.89 |
Isotope pattern for [AuBr3]2
The chart below shows the calculated isotope pattern for the formula [AuBr3]2 with the most intense ion set to 100%.
References
The data on these compounds pages are assembled and adapted from the primary literature and several other sources including the following.
- R.T. Sanderson in Chemical Periodicity, Reinhold, New York, USA, 1960.
- N.N. Greenwood and A. Earnshaw in Chemistry of the Elements, 2nd edition, Butterworth, UK, 1997.
- F.A. Cotton, G. Wilkinson, C.A. Murillo, and M. Bochmann, in Advanced Inorganic Chemistry, John Wiley & Sons, 1999.
- A.F. Trotman-Dickenson, (ed.) in Comprehensive Inorganic Chemistry, Pergamon, Oxford, UK, 1973.
- R.W.G. Wyckoff, in Crystal Structures, volume 1, Interscience, John Wiley & Sons, 1963.
- A.R.West in Basic solid state chemistry Chemistry, John Wiley & Sons, 1999.
- A.F. Wells in Structural inorganic chemistry, 4th edition, Oxford, UK, 1975.
- J.D.H. Donnay, (ed.) in Crystal data determinative tables, ACA monograph number 5, American Crystallographic Association, USA, 1963.
- D.R. Lide, (ed.) in Chemical Rubber Company handbook of chemistry and physics, CRC Press, Boca Raton, Florida, USA, 77th edition, 1996.
- J.W. Mellor in A comprehensive treatise on inorganic and theoretical chemistry, volumes 1-16, Longmans, London, UK, 1922-1937.
- J.E. Macintyre (ed.) in Dictionary of inorganic compounds, volumes 1-3, Chapman & Hall, London, UK, 1992.